A great place for information on all things Google is Google itself.
http://www.google.com/support/webmasters/bin/topic.py?topic=8456 "My Site and Google" contains great information on how to get configure your site to be Google Friendly.
Google allows you to upload a site index to tell it where all your pages are.
Here is where you can add your WebSite to Google's "to be indexed" list.
Also there is a lot of information on how to set up a site to work with Google.
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